Rainwater is saturated with oxygen , nitrogen and carbon dioxide and is generally slightly acidic.
If the groundwater remain long contact with the CaCO3 Calcite and Dolomite CO3Ca . Mg lead to an increase in calcium, magnesium and bicarbonates.
The aluminosilicates increase the concentrations of sodium, magnesium, calcium and silica .
If it matches that much gypsum and anhydrite are based mineral sulfates , they can do to dominate the sulfate ion on bicarbonate ion, but that's not normal.
surface waters are much more exposed to pollution from human activity and contain, in addition to organic matter, all kinds of products industrial or agricultural origin.
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